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Updated ozone absorption cross section will reduce air quality compliance

As an air pollutant, O3 is monitored photometrically to assess compliance with air quality legislation. A recent study found a 1.8% reduction in its absorption cross section, which would lead to an equivalent increase in observed O3 concentrations. We estimate this would increase the number of sites out of compliance with air quality regulations in the EU and US by 20%. We draw attention to how small changes in gas metrology impacts attainment and compliance with legal air quality standards.

Magnetospheric conditions near the equatorial footpoints of proton isotropy boundaries

Adaptive magnetospheric models based on THEMIS magnetic observations made at 6-9Re in the nightside magnetosphere are used to map the magnetically conjugate 30 and 80keV proton isotropy boundaries (IBs) to investigate the value of Kib=Rc/rc (magnetic curvature radius to particle gyroradius) in the neutral sheet at the IB generation place. For the most accurate mapping, the group Kib spread spans from 4 to 32; its median value is ~13, slightly larger than Kib8 expected for current sheet scatter.

Reviews and syntheses: Effects of permafrost thaw on Arctic aquatic ecosystems

In this review, we give an overview of the current state of knowledge regarding how permafrost thaw affects aquatic systems. We describe the general impacts of thaw on aquatic ecosystems, pathways of organic matter and contaminant release and degradation, resulting emissions and burial, and effects on ecosystem structure and functioning. We conclude with an overview of potential climate effects and recommendations for future research.

Observations of the spectral dependence of linear particle depolarization ratio of aerosols using NASA Langley airborne High Spectral Resolution Lidar

The manuscript describes measurements of particle depolarization ratio from the NASA airborne HSRL-2 at three wavelengths, for two dust cases and a smoke case. Differences in the spectral dependence of particle depolarization ratio are due to the sizes of the non-spherical particles, large for dust and small for smoke. The large depolarization at 355nm for smoke has not been previously reported and may impact aerosol typing when only a single wavelength is available.

Biodegradability of dissolved organic carbon in permafrost soils and aquatic systems: a meta-analysis

We found that dissolved organic carbon (DOC) in arctic soils and aquatic systems is increasingly degradable with increasing permafrost extent. Also, DOC seems less degradable when moving down the fluvial network in continuous permafrost regions, i.e. from streams to large rivers, suggesting that highly bioavailable DOC is lost in headwater streams. We also recommend a standardized DOC incubation protocol to facilitate future comparison on processing and transport of DOC in a changing Arctic.

pH up-regulation as a potential mechanism for the cold-water coral Lophelia pertusa to sustain growth in aragonite undersaturated conditions

We investigated the ability of cold-water corals to deal with changes in ocean pH. We uniquely combined morphological assessment with boron isotope analysis to determine if changes in growth are related to changes in control of calcification pH. We found that the cold-water coral Lophelia pertusa can maintain the skeletal morphology, growth patterns as well as internal calcification pH. This has important implications for their future occurrence and explains their cosmopolitan distribution.

A dynamical systems approach to the surface search for debris associated with the disappearance of flight MH370

The disappearance of Malaysia Airlines flight MH370 on 8 March 2014 is one of the great mysteries of our time. The most relevant aspect is that not a piece of debris was found during the intensive surface search carried out for roughly 2 months following the crash. By combining different ocean data with dynamical systems tools, we propose a revised search strategy by showing why debris could not have been expected in some targeted search areas and determining regions where debris could be.

Laboratory evidence of organic peroxide and peroxyhemiacetal formation in the aqueous phase and implications for aqueous OH

This paper demonstrates organic peroxide and peroxyhemiacetal formation during aqueous photooxidation of methylglyoxal using ultra-high-resolution Fourier transform ion cyclotron resonance electrospray ionization mass spectrometry (FTICR-MS). Then, we provide simulation results of organic peroxide/peroxyhemiacetal formation in clouds and wet aerosols and discuss organic peroxides as a source of condensed-phase OH radicals and as a contributor to aqueous secondary organic aerosol (SOA).

Ice water content vertical profiles of high-level clouds: classification and impact on radiative fluxes

We discuss the shape of ice water content (IWC) vertical profiles in high ice clouds and its effect on radiative properties of these clouds, both in short- and in long-wave bands (SW and LW). We suggest a set of primitive shapes (rectangular, isosceles trapezoid, lower and upper triangle) and propose a statistical parameterization using ice water path (IWP) as a single parameter. We estimate and explain simulated differences in LW/SW atmospheric radiances for suggested IWC shapes.

Reducing uncertainties in projections of Antarctic ice mass loss

Projections of Antarctic dynamics and contribution to sea-level rise are evaluated in the light of intercomparison exercises dedicated to evaluate models’ ability of representing coastal changes. Uncertainties in projections can be substantially decreased if a selection of models is made and models that are unqualified for the representation of coastal dynamics are excluded.

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