Atmospheric histories, growth rates and solubilities in seawater and other natural waters of the potential transient tracers HCFC-22, HCFC-141b, HCFC-142b, HFC-134a, HFC-125, HFC-23, PFC-14 and PFC-116 Ocean Science DOI 10.5194/os-15-33-2019 11 January 2019 Use of CFCs as oceanic transient tracers is difficult for recently ventilated water masses as their atmospheric mole fractions have been decreasing. To explore novel tracers, we synthesized consistent annual mean atmospheric histories of HCFC-22, HCFC-141b, HCFC-142b, HFC-134a, HFC-125, HFC-23, PFC-14 (CF4) and PFC-116 in both hemispheres and reconstructed their solubility functions in water and seawater. This work is also potentially useful for tracer studies in a range of natural waters. Read more
Structural changes in the shallow and transition branch of the Brewer–Dobson circulation induced by El Niño Atmospheric Chemistry and Physics DOI 10.5194/acp-19-425-2019 11 January 2019 This paper assesses the structural changes in the shallow and transition branches of the BDC induced by El Nino using the Lagrangian model simulations driven by ERAi and JRA-55 combined with MLS observations. We found a clear evidence of a weakening of the transition branch due to an upward shift in the dissipation height of the planetary and gravity waves and a strengthening of the shallow branch due to enhanced GW breaking in the tropics–subtropics and PW breaking at high latitudes. Read more
Refining physical aspects of soil quality and soil health when exploring the effects of soil degradation and climate change on biomass production: an Italian case study SOIL DOI 10.5194/soil-5-1-2019 10 January 2019 This study is restricted to soil physical aspects of soil quality and health with the objective to define procedures with worldwide rather than only regional applicability, reflecting modern developments in soil physical research and focusing on important questions regarding possible effects of soil degradation and climate change. Read more
Exploring the use of underground gravity monitoring to evaluate radar estimates of heavy rainfall Hydrology and Earth System Sciences DOI 10.5194/hess-23-93-2019 8 January 2019 In this study, we explore the use of an underground superconducting gravimeter as a new source of in situ observations for the evaluation of radar-based precipitation estimates. The comparison of radar and gravity time series over 15 years shows that short-duration intense rainfall events cause a rapid decrease in the measured gravity. Rainfall amounts can be derived from this decrease. The gravimeter allows capture of rainfall at a much larger spatial scale than a traditional rain gauge. Read more
The onset of neoglaciation in Iceland and the 4.2 ka event Climate of the Past DOI 10.5194/cp-15-25-2019 8 January 2019 Compositing climate proxies in sediment from seven Iceland lakes documents abrupt summer cooling between 4.5 and 4.0 ka, statistically indistinguishable from 4.2 ka. Although the decline in summer insolation was an important factor, a combination of superposed changes in ocean circulation and explosive Icelandic volcanism were likely responsible for the abrupt perturbation recorded by our proxies. Lake and catchment proxies recovered to a colder equilibrium state following the perturbation. Read more
A shape model of internally mixed soot particles derived from artificial surface tension Atmospheric Measurement Techniques DOI 10.5194/amt-12-107-2019 7 January 2019 We developed a shape model of coated soot particles and created a dataset of their optical properties. To simulate the detailed shape properties of mixtures of soot aggregates and adhered water-soluble substances, we propose a simple model of surface tension derived from the artificial surface potential. The results of some single-scattering properties including lidar backscattering were discussed. Read more
ESD Ideas: Photoelectrochemical carbon removal as negative emission technology Earth System Dynamics DOI 10.5194/esd-10-1-2019 4 January 2019 Current CO2 emission rates are incompatible with the 2 °C target for global warming. Negative emission technologies are therefore an important basis for climate policy scenarios. We show that photoelectrochemical CO2 reduction might be a viable, high-efficiency alternative to biomass-based approaches, which reduce competition for arable land. To develop them, chemical reactions have to be optimized for CO2 removal, which deviates from energetic efficiency optimization in solar fuel applications. Read more
What climate signal is contained in decadal- to centennial-scale isotope variations from Antarctic ice cores? Climate of the Past DOI 10.5194/cp-14-2053-2018 20 December 2018 Proxy data on climate variations contain noise from many sources and, for reliable estimates, we need to determine those temporal scales at which the climate signal in the proxy record dominates the noise. We developed a method to derive timescale-dependent estimates of temperature proxy signal-to-noise ratios, which we apply and discuss in the context of Antarctic ice-core records but which in general are applicable to a large set of palaeoclimate records. Read more
Photochemical box modelling of volcanic SO2 oxidation: isotopic constraints Atmospheric Chemistry and Physics DOI 10.5194/acp-18-17909-2018 18 December 2018 Volcanic sulfur can have climatic impacts for the planet via sulfate aerosol formation, leading also to pollution events. We provide model constraints on tropospheric volcanic sulfate formation, with implications for its lifetime and impacts on regional air quality. Oxygen isotope investigations from our model suggest that in the poor tropospheric plumes of halogens, the O2/TMI sulfur oxidation pathway might significantly control sulfate production. The produced sulfate has no isotopic anomaly. Read more
Retreat of Thwaites Glacier, West Antarctica, over the next 100 years using various ice flow models, ice shelf melt scenarios and basal friction laws The Cryosphere DOI 10.5194/tc-12-3861-2018 11 December 2018 Thwaites Glacier, West Antarctica, has experienced rapid grounding line retreat and mass loss in the past decades. In this study, we simulate the evolution of Thwaites Glacier over the next century using different model configurations. Overall, we estimate a 5 mm contribution to global sea level rise from Thwaites Glacier in the next 30 years. However, a 300% uncertainty is found over the next 100 years, ranging from 14 to 42 mm, depending on the model setup. Read more